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Nuclear magnetic resonance (NMR) was employed to study the zinc-ligand coordination in Zn(2+)- and Cd(2+)-substituted dipeptides in model aqueous solution. The NMR data demonstrate that the zinc atom interacts with two distinct ligand groups, one of which is a nonpolar NH-acetyl group; the other is a polar NH- or NH2-group. The results were compared with those obtained for Cd(2+) and Hg(2+) ions, providing a possible model for the coordination of Zn(2+) to biological systems.Two infant boys were rushed to hospitals with bad coughs in separate incidents Saturday morning.
One was rushed to Toronto’s Hospital for Sick Children and the other to East Avenue Hospital, paramedics said.
One child was believed to be suffering from a common cold, while the other had an ear infection, paramedics said.
Toronto paramedics said they were dispatched to two separate incidents on Sunday morning. One child was rushed to Hospital for Sick Children, while the other was taken to East Avenue Hospital. (Matthew Kupfer/CBC News)
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